Product ID:D-LIMONENE-TECHNICAL GRADE
MSDS Date:01/10/1994
FSC:6810
NIIN:00N060515
MSDS Number: BXSZQ

FLORIDA CHEMICAL CO INC

475 DAKOTA AVE NORTH
LAKE ALFRED, FL 33850
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 813-956-1843

Cage: 2W723

FLORIDA CHEMICAL SUPPLY INC

997 TAMPA, FL 33610-5635 US

Telephone: 813-988-4890

Cage: 2W723

CYCLOHEXENE, 1-METHYL-4-(1-METHYLETHENYL)-, (R)-;

CAS: 5989-27-5

RTECS: GW6360000

OSHA PEL N/K

ACGIH TLV: N/K

OCCASNLY CHIP & FALL TO BOTTOM OF CONTR AFTER

RTECS: 9999999ZZ

STRAINER TO CATCH SML PIECES OF LINER BEFORE

RTECS: 9999999ZZ

DO NOT WELD OR CUT EMPTY CONTAINERS

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50 (ORAL RAT): > 5 G/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED. INGESTION
MAY CAUSE VOMITING, HEADACHE, AND OTHER MEDICAL PROBLEMS. MAY BE
IRRITATING TO SKIN AND EYES. SKIN CONTACT MAY CAUSE SLIGHT REDNESS.
CONTAINS A POTENTIAL SKIN SE NSITIZER. EYE CONTACT CAN CAUSE
MODERATE TO HIGH IRRITATION. INHALATION CAN CAUSE NOSE, THROAT, AND
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: RESPIRATORY TRACT IRRITATION,
COUGHING, AND HEADACHE. CHRONIC: PROLONGED OR REPEATED EXPOSURE CAN
CAUSE DRYING, DEFATTING, AND DERMATITIS OF SKIN.
Medical Cond Aggravated by Exposure:NONE KNOWN.

First Aid:EYES: REMOVE CONT LENSES AT ONCE. FLUSH W/WATER FOR AT LEAST
15 MIN. IF IRRIT PERSISTS, SEE MD. SKIN: WASH AFFECTED AREA
W/COPIOUS AMTS OF SOAP & WATER. CALL MD IF IRRIT DEVELOPS.
COMPLETELY DECONTAM CLTHG, SHOES, & LEATHER GOODS BEFORE
REUSE/DISCARD. INGEST: DO NOT INDUCE VOMIT. RINSE MOUTH W/WATER,
THEN DRINK ONE GLASS OF WATER. CONT MD IMMED. NEVER GIVE ANYTHING
BY MOUTH IF VICTIM (SUP DAT)

Flash Point Method:TCC
Flash Point:115F,46C
Lower Limits:0.7%
Upper Limits:6.1%
Extinguishing Media:CARBON DIOXIDE, FOAM AND DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . DO NOT USE WATER. HANDLE AS AN OIL FIRE,
CLASS B FIRE PROCEDURES.
Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID. KEEP AWAY FROM HEAT,
SPARKS, AND OPEN FLAME. GUARD AGAINST SPONTANEOUS COMBUSTION OF
IMPROPERLY DISCARDED OILY RAGS.

Spill Release Procedures:USE PROT GLOVES TO AVOID SKIN CONT. SML SPILLS
CAN BE WIPED UP. LGE SPILLS SHOULD BE ABSORBED BY DIRT, SAND/OTHER
SUITABLE ABSORB FOR DISP. DO NOT HOSE SPILLS DOWN DRAINS,
SEWERS/WATERWAYS. PROD MAY B E TOX TO AQUATIC ORGANISMS. MOVE (SUP
DAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN SPRINKLERED WAREHOUSE. AVOID
CONT W/INCOMPATIBLE CHEM. STORE IN TIGHTLY SEALED, FULL CONTRS.
Other Precautions:BEST TO STORE IN GLASS, TIN-LINED, STAINLESS
STEEL/EPOXY-LINED CONTRS TO PRESERVE QUALITY. PROD MAY EXPAND
SLIGHTLY IN STOR CAUSING PRESS TO BUILD IN CONTR. OPEN CONTR
CAREFULLY IF PROD APPEARS TO BE UNDER PRESS. DRUM LINING MAY (ING
2)

Respiratory Protection:NOT NORMALLY REQUIRED, BUT IF VAPOR
CONCENTRATION BECOMES HIGH, USE NIOSH/MSHA APPROVED SELF-CONTAINED
AIR MASK.
Ventilation:LOCAL EXHAUST SHOULD BE ADEQUATE. MECHANICAL VENTILATION
OTHERWISE RECOMMENDED IF NECESSARY.
Protective Gloves:CHEM-RESIST (NEOPRENE, PVC/BUTYL).
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
SPEC GRAV:0.838-0.843 @ 25C. FIRST AID PROC:IS UNCON, RAPIDLY LOSING
CONSCIOUSNESS/CONVULSING. INHAL:EVACUATE TO FRESH AIR. IF SYMP
PERSIST, SEEK MED ATTN. SPILL PROC:LEAKING CONTRS TO WELL VENT
AREA. NO SMKNG. ELIMINATE ANY SOURCE OF IGNIT. MIN INHAL. USE
NIOSH/MSHA APPRVD RESP PROT DEVICE. CAUTION:SLIPPERY ON FLOOR.

Boiling Pt:B.P. Text:310F,154C
Vapor Pres:2 @ 20C
Spec Gravity:(SUP DAT)
Evaporation Rate & Reference:<1 (ETHER=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR LIQUID, VARIABLE COLORLESS TO YELLOW CAST
WITH STRONG CITRUS ODOR
Percent Volatiles by Volume:95+

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS & ACIDIC AGENTS, INCL ACIDIC CLAYS, PEROXIDES,
HALOGENS, VINYL CHLORIDE, & IODINE PENTAFLUORIDE.
Stability Condition to Avoid:EXCESSIVE HEAT. POLYMERIZATION CATALYSTS
SUCH AS ALUMINUM CHLORIDE AND ACIDIC CLAYS.
Hazardous Decomposition Products:SMOKE MAY BE ACRID & FUME IRRIT.
BURNING GENERATES CARBON MONOXIDE, CARBON DIOXIDE, & SMOKE. PROD
NOT AN OXYGEN DONOR.

Waste Disposal Methods:INCINERATE OR DISPOSE IN ACCORDANCE WITH LOCAL,
STATE, AND FEDERAL REGULATIONS.

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particular situation.